Acidic wood extractives accelerate the curing process of emulsion polymer isocyanate adhesives
نویسندگان
چکیده
Emulsion polymer isocyanate (EPI) adhesive is one of the most widely used structural adhesives in woodworking industry. However, there has been a lack knowledge on how EPI-adhesive interacts with chemical constituents wood, particular, wood extractives that are known to influence bonding quality. In this study, interactions water extracts and selected from European species were systematically investigated using different analytical techniques. While alterations curing properties pure EPI-adhesive-extract mixtures revealed by situ rheology Fourier-transform infrared spectroscopy, evolved gas analysis, pyrolysis-gas chromatography/mass spectrometry, solid-state 13C nuclear magnetic resonance performed for analyzing final composition cured adhesive. Moreover, extraction mechanical performance was tested tensile-shear tests. The study significant between tannin-rich, acidic extracts. chestnut oak catalyzed reactions led huge increase viscosity. These might affect quality, example, penetration depth formation strength, therefore, careful attention required when surfaces.
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ژورنال
عنوان ژورنال: Journal of Applied Polymer Science
سال: 2022
ISSN: ['1097-4628', '0021-8995']
DOI: https://doi.org/10.1002/app.52189